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Ultrahigh-current-density niobium disulfide catalysts for hydrogen evolution

Research output: Contribution to journalArticle

  • Jieun Yang
  • Abdul Rahman Mohmad
  • Yan Wang
  • Raymond Fullon
  • Xiuju Song
  • Fang Zhao
  • Ibrahim Bozkurt
  • Mathias Augustin
  • Elton J. G. Santos
  • Hyeon Suk Shin
  • Wenjing Zhang
  • Damien Voiry
  • Hu Young Jeong
  • Manish Chhowalla

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Original languageEnglish
Pages (from-to)1309-1314
Number of pages6
JournalNature Materials
Issue number12
Publication statusPublished - 26 Aug 2019


Metallic transition metal dichalcogenides (TMDs)1,2,3,4,5,6,7,8 are good catalysts for the hydrogen evolution reaction (HER). The overpotential and Tafel slope values of metallic phases and edges9 of two-dimensional (2D) TMDs approach those of Pt. However, the overall current density of 2D TMD catalysts remains orders of magnitude lower (~10–100 mA cm−2) than industrial Pt and Ir electrolysers (>1,000 mA cm−2)10,11. Here, we report the synthesis of the metallic 2H phase of niobium disulfide with additional niobium (2H Nb1+xS2, where x is ~0.35)12 as a HER catalyst with current densities of >5,000 mA cm−2 at ~420 mV versus a reversible hydrogen electrode. We find the exchange current density at 0 V for 2H Nb1.35S2 to be ~0.8 mA cm−2, corresponding to a turnover frequency of ~0.2 s−1. We demonstrate an electrolyser based on a 2H Nb1+xS2 cathode that can generate current densities of 1,000 mA cm−2. Our theoretical results reveal that 2H Nb1+xS2 with Nb-terminated surface has free energy for hydrogen adsorption that is close to thermoneutral, facilitating HER. Therefore, 2H Nb1+xS2 could be a viable catalyst for practical electrolysers.

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